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Wednesday, March 30th, 2022

Luke Kong

Using Chaotic Interrogation and Attractor Deformation to Determine Damage Location and Extent

One promising approach for detecting damage in non-linear systems is to use chaotic interrogation: a system is excited by a chaotic signal and the resulting response is used to infer the damaged state. In this work, a new method based on boundary transformation vectors (BTVs) is explored as a way of simultaneously ascertaining both damage level and location.
The process works as follows: (1) The system is excited by a chaotic signal. (2) The system response is recorded at some location. (3) The peaks of the system response are sampled and combined to create a picture of the chaotic signal known as a Poincare section. (4) By comparing the boundaries of Poincare sections for different damage states using BTVs, the damage level and location can be inferred.
Three different systems were explored: a 5-body mass-spring-damper model, a simulated cantilever beam, and a physical cantilever beam. To excite these systems, a chaotic Brusselator signal was chosen. Displacements were used as output signals in the simulated systems; for the physical beam, acceleration was used.
Results from the simulated systems demonstrate that chaotic interrogation and BTV analysis can be used to ascertain system damage in stiffness or damping and, in some cases, location because Poincare boundary changes scale with the level of damage. For the physical beam, damage extent was discernible for particular combinations of damage and observer locations. However, indications of damage location were inconsistent.
Overall, these results demonstrate that the BTV method has promise and can be improved with further research.

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Tuesday, March 29th, 2022

Nolan Morrison

Factors That Influence Successful Base Catalyzed Thiol-ene Hydrogel Synthesis

Ethoxylated trimethylolpropane tri-3-mercaptopropionate (ETTMP) and poly(ethylene glycol) diacrylate (PEGDA)-based hydrogels are a promising candidate for injectable, localized drug delivery due to the potential for non-swelling behavior and controllable drug release properties. However, we find that existing literature synthesis methods suffer from slow gelation times or a lack of reproducible procedures. In this work, we present a repeatable synthesis procedure, along with a sensitivity analysis of the major variables that impact successful synthesis. Our methods allow the hydrogels to be reliably synthesized in a polymer concentration range of 15 to 90 wt.%, resulting in gelation times between 2 min and 1 h with equilibrium moduli between 3.5 and 190 kPa. Furthermore, base-catalyzed conjugate Michael curing led to 16.35 min and 1.67 min gelation times for buffer pH values of 6.5 and 8, respectively. Additionally, we show that ETTMP purification directly controls the concentration of mercaptopropionic acid (MPA) necessary to inhibit the Michael addition. Lastly, we find that a stoichiometric mixture of ETTMP and PEGDA has a freezing point range of -17.9 ºC to -27.2 ºC and can be stored at -20 ºC for 2 months without crosslinking, as opposed to 2 days at room temperature, making storage and shipment of mixtures possible.

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